Reaction of oxiranes with cyclodextrins under high-energy ball-milling conditions
نویسندگان
چکیده
منابع مشابه
Synthesis of Randomly Substituted Anionic Cyclodextrins in Ball Milling.
A number of influencing factors mean that the random substitution of cyclodextrins (CD) in solution is difficult to reproduce. Reaction assembly in mechanochemistry reduces the number of these factors. However, lack of water can improve the reaction outcomes by minimizing the reagent's hydrolysis. High-energy ball milling is an efficient, green and simple method for one-step reactions and usual...
متن کاملGreen High-Yielding One-Pot Approach to Biginelli Reaction under Catalyst-Free and Solvent-Free Ball Milling Conditions
A simple, green, and efficient approach was used to synthesize 3,4-dihydropyrimidines derivatives. We showed that the application of the planetary ball milling method with a ball-to-reagent weight ratio of 8 for the Biginelli reaction provides 3,4-dihydropyrimidines derivatives with excellent yields (>98%) in a short reaction time from the one-pot, three-component condensation of aldehydes, eth...
متن کاملFormation of glassy Ti50Cu20Ni24Si4B2 alloy by high-energy ball milling
The elemental powder mixtures with a nominal composition of Ti50Cu20Ni24Si4B2 can be amorphized under high-energy ball milling. A well-defined glass transition before crystallization appears in the obtained amorphous phase during heating in a differential scanning calorimeter. Awide supercooled liquid region DTx is available to be about 57 K. Crystallization of the ballmilled amorphous phase wa...
متن کاملEVect of high energy ball milling on titanium– hydroxyapatite powders
to bone are concerned are brittle materials as exempli ed by hydroxyapatite and ‘Bioglass’. Bioactive coatings are This paper reports on an investigationof the potential employed on metal implants to facilitate bonding to bone use of high energy ball milling (HEBM) for the while retaining the good combination of mechanical production of homogeneous mixtures of titanium/ properties associated w...
متن کاملQuenching ilmenite with a high-temperature and high-pressure phase using super-high-energy ball milling
The mass production of highly dense oxides with high-temperature and high-pressure phases allows us to discover functional properties that have never been developed. To date, the quenching of highly dense materials at the gramme-level at ambient atmosphere has never been achieved. Here, we provide evidence of the formation of orthorhombic Fe2TiO4 from trigonal FeTiO3 as a result of the high-tem...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Beilstein Journal of Organic Chemistry
سال: 2019
ISSN: 1860-5397
DOI: 10.3762/bjoc.15.145